Compounds with Sulfur of Oxidation Number IV (Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition) (Part 7) pdf epub fb2

Compounds with Sulfur of Oxidation Number IV (Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition) (Part 7) by - epub fb2 djvu

Author: -
Title: Compounds with Sulfur of Oxidation Number IV (Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition) (Part 7)
ISBN: 3540936246
ISBN13: 978-3540936244
Other Formats: lrf lrf doc mbr
Pages: 338 pages
Publisher: Springer; 8 edition (December 21, 1990)
Language: English
Size EPUB version: 1272 kb
Size FB2 version: 1601 kb
Category: Science & Math
Subcategory: Chemistry

Part of an encyclopaedic reference on inorganic and organometallic chemistry, this present volume continues a series on acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The description of sulfur-nitrogen compounds with 2-co-ordinate sulfur is continued with the sulfur diimides and sulfur diimide anions, their transition metal complexes, and radicals, cations and radical anions derived from sulfur diimides. The examination of sulfur diimides begins with the parent compound HN=S=NH, and the sulfur diimide anion [N=S=N]2-, whose potassium salt can act as a starting compound for the preparation of acyclic and cyclic sulfur diimides and their transition metal complexes. The following sections of the text deal with sulfur diimides bearing substituents at the nitrogen atoms which involve elements of the main groups VII to VIII. There are numerous examples of symmetrically and unsymmetrically N,N'-disubstituted sulfur diimides. The volume concludes with a detailed description of the class of N,N'-diorganyl-sulfur diimides, RN=S=NR'. The main importance of these compounds is their function as intermediates for organic synthesis.

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